If you get one of the larger ones and are able to erect it on a mast, and replace the suspension with suitably reinforced sport springs all round, then with suitable rigging and a fair wind you could also use it as a sail for propulsion as long as there aren't other vehicles preventing you from tacking. /sarcasm off.
It's an interesting idea but I think you probably - as suggested above - need to work out the power generation characteristics of the alternator in normal running, and then extrapolate this into the size and efficiency of panel that you would require under perfect conditions rather than just choosing an arbitrary number such as 100W. This will also normally be dictated by power requirement of objects such as the steering pump, aircon, electric heater (BHC) and so on, and even if these are removed, bear in mind that a low battery causes all manner of warning lights to come on as ECUs get confused, so imagine that this would be happening constantly unless you are able to either stabilise the supply or make the system more tolerant. Then allow for UK conditions so increase the specification by a contingency factor.
Looking forward to the project thread. Good luck!