Hi Les, I'm sure there will be much wiser people than me come along, but it could be a head gasket, the expansion bottle seal is damaged or worn? broken coolant sensor, water pump gone?. Do you get hot air in the car? are the coolant pipes (the large ones running to the rad hot or cold? Is the water coming out of the lid of the expansion bottle or out of the overflow (that you can tell).
Loads of questions, but all will help.